Crystal structure of bis(2-chloro-6-fluorobenzoato)bis(pyridine)copper(II), CU(C7H3ClFO2)2(C5NH5)2
نویسندگان
چکیده
منابع مشابه
Crystal structure of 3-bromomethyl-2-chloro-6-(dibromomethyl)quinoline
In the title compound, C11H7Br3ClN, the quinoline ring system is approximately planar (r.m.s. = 0.011 Å). In the crystal, mol-ecules are linked by C-H⋯Br inter-actions forming chains along [10-1]. The chains are linked by C-H⋯π and π-π inter-actions involving inversion-related pyridine rings [inter-centroid distance = 3.608 (4) Å], forming sheets parallel to (10-1). Within the sheets, there are...
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In the title salt, C5H7N(+)·C6H3ClNO(-), the 2-amino-pyri-din-ium cation inter-acts with the carboxyl-ate group of the 6-chloro-nicotinate anion through a pair of independent N-H⋯O hydrogen bonds, forming an R 2 (2)(8) ring motif. In the crystal, these dimeric units are connected further via N-H⋯O hydrogen bonds, forming chains along [001]. In addition, weak C-H⋯N and C-H⋯O hydrogen bonds, toge...
متن کاملCrystal structure of ethyl 2-chloro-6-methylquinoline-3-carboxylate
In the title compound, C13H12ClNO2, the dihedral angle between the planes of the quinoline ring system (r.m.s. deviation = 0.029 Å) and the ester group is 54.97 (6)°. The C-O-C-Cm (m = meth-yl) torsion angle is -140.62 (16)°. In the crystal, mol-ecules inter-act via aromatic π-π stacking [shortest centroid-centroid separation = 3.6774 (9) Å] generating (010) sheets.
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The title compound, C13H14ClNO3, crystallizes with Z' = 2 in the space group Pca21, but a search for possible additional crystallographic symmetry found none. However, the crystal structure exhibits pseudosymmetry as the two independent mol-ecules are related by an approximate but non-crystallographic inversion located close to (0.38, 0.26, 1/2) in the selected asymmetric unit, and the structur...
متن کاملCrystal structure of 4-chloro-2-iodoaniline
In the crystal structure of the title compound, C6H5ClIN, the amino group engages in N-H⋯N hydrogen bonding, creating [100] chains. A Cl⋯I contact is observed [3.7850 (16) Å]. The parallel planes of neigbouring mol-ecules reveal highly offset π-stacking characterized by a centroid-centroid distance of 4.154 (1), a centroid-to-plane distance of 3.553 (3) and ring-offset slippage of 2.151 (6) Å.
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ژورنال
عنوان ژورنال: Zeitschrift für Kristallographie - New Crystal Structures
سال: 2003
ISSN: 2197-4578,1433-7266
DOI: 10.1524/ncrs.2003.218.jg.31